In this example, it's demonstrated how to use the GroupDescription property to automatically group items generated from a collection. To accomplish this task, it's necessary to set GroupDescription to a property name by which items should be grouped.
Another solution to group items is to bind NavBarControl to a source that implements ICollectionView and specify GroupDescriptions:
[C#]CollectionViewEmployees.GroupDescriptions.Add(newPropertyGroupDescription("Department"));
If you wish to specify ItemsSource for each group separately, use the approach demonstrated at How to: Generate NavBarControl Groups and Items from a Collection